It's similar to "call", "gather" or "attract" something. For example: "I'll invoke a spell" (= I'll cast a spell), "I invoke the president for this meeting". Well, I cannot gave better examples, but I hope that can help you.
Both words have a similar idea, but have a specify situation that you can use one of them. In my country for example, we often use "folks" instead "we" to talk about the first person of plural. This makes my languages seems to poor. But it's fine.
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